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Rates of reaction

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Some reactions are explosive, others take years. Five factors control how fast a reaction goes.

Measuring rate

mean rate = amount of product formedtime (or reactant used up ÷ time)
Measure gas volume with a gas syringe, mass loss on a balance, or time for a cross to disappear under a cloudy solution.

Factors

Rate increases with higher temperature, higher concentration (or pressure for gases), larger surface area (smaller pieces) and a catalyst.

Graphs

On a graph of product against time, a steeper gradient means a faster rate.
The line levels off when the reaction stops because a reactant has run out.
For a tangent to a curve (Higher), rate = gradient of the tangent.
Worked example

A reaction produces 60 cm3 of gas in 30 s. Find the mean rate.

  1. rate = 60 ÷ 30

Answer: 2 cm3/s

Key idea

Rate = amount ÷ time. Temperature, concentration or pressure, surface area and catalysts all increase rate. A steeper graph means a faster reaction.

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