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Energy changes in reactions

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Every reaction involves an energy change. Some heat their surroundings, others cool them down.

Exothermic and endothermic

Exothermic: gives out heat; the temperature of the surroundings rises. Combustion, neutralisation.
Endothermic: takes in heat; the temperature falls. Thermal decomposition, dissolving ammonium nitrate.

Reaction profiles

Exothermic: products lower than reactants. Endothermic: products higher.
The hump shows the activation energy.

Bond energies (Higher)

Breaking bonds takes in energy; making bonds releases energy.
Energy change = energy to break bonds โˆ’ energy released making bonds
A negative answer means exothermic.
Worked example

Breaking bonds needs 2648 kJ and making bonds releases 3466 kJ. Find the energy change.

  1. 2648 โˆ’ 3466

Answer: โˆ’818 kJ (exothermic)

Key idea

Exothermic reactions release heat (temperature rises); endothermic reactions absorb it (temperature falls). Energy change = bonds broken โˆ’ bonds made; negative means exothermic.

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