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Yield and atom economy

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Chemists want as much product as possible with as little waste as possible. Yield and atom economy measure this. Separate Chemistry only.

Percentage yield

percentage yield = actual yieldtheoretical yield × 100
Yields are below 100% because the reaction may be reversible, some product is lost when separating, or there are side reactions.

Atom economy

atom economy = M_r of desired producttotal M_r of all reactants × 100
A high atom economy means less waste, which is better for the environment and cheaper.

Choosing a route

Industry compares atom economy, yield, rate, equilibrium position, and the usefulness of by-products.
Worked example

Theoretical yield is 20 g; actual yield is 15 g. Find the percentage yield.

  1. 1520 × 100

Answer: 75%

Key idea

Percentage yield = actual ÷ theoretical × 100. Atom economy = M_r of wanted product ÷ total M_r of reactants × 100. Higher atom economy means less waste.

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