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Metallic bonding

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Metals have their own kind of bonding, which explains why they conduct electricity and can be hammered into shape.

The metallic lattice

In a 2-D diagram, a metal is drawn as rows of positive ions surrounded by a 'sea' of delocalised electrons (the outer electrons that have left the atoms).
The ions are arranged in a regular pattern (a lattice).

Metallic bonding

Metallic bonding is the strong electrostatic attraction between the positive metal ions and the delocalised electrons.
This attraction is strong, so most metals have high melting points.

Explaining properties

Electrical conductivity: the delocalised electrons can move through the structure, carrying charge.
Malleability: the layers of positive ions can slide over each other when a force is applied. The delocalised electrons still hold them together, so the metal changes shape instead of breaking.
Worked example

Explain why copper can be hammered into a thin sheet without breaking.

  1. Copper has layers of positive ions in a sea of delocalised electrons.
  2. The layers can slide over each other.
  3. The metallic bonding is not broken because the electrons still attract the ions.

Answer: Layers of ions slide over each other while the delocalised electrons keep holding them together.

Key idea

Metals are lattices of positive ions in a sea of delocalised electrons. Metallic bonding is the electrostatic attraction between them. Delocalised electrons move to conduct electricity; layers of ions slide, making metals malleable.

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